全文获取类型
收费全文 | 20985篇 |
免费 | 2231篇 |
国内免费 | 1976篇 |
专业分类
化学 | 16978篇 |
晶体学 | 604篇 |
力学 | 135篇 |
综合类 | 104篇 |
数学 | 44篇 |
物理学 | 7327篇 |
出版年
2024年 | 16篇 |
2023年 | 187篇 |
2022年 | 359篇 |
2021年 | 597篇 |
2020年 | 703篇 |
2019年 | 663篇 |
2018年 | 505篇 |
2017年 | 570篇 |
2016年 | 896篇 |
2015年 | 707篇 |
2014年 | 825篇 |
2013年 | 1757篇 |
2012年 | 1441篇 |
2011年 | 1235篇 |
2010年 | 1158篇 |
2009年 | 1348篇 |
2008年 | 1365篇 |
2007年 | 1607篇 |
2006年 | 1463篇 |
2005年 | 1159篇 |
2004年 | 1057篇 |
2003年 | 847篇 |
2002年 | 687篇 |
2001年 | 462篇 |
2000年 | 454篇 |
1999年 | 390篇 |
1998年 | 402篇 |
1997年 | 324篇 |
1996年 | 331篇 |
1995年 | 345篇 |
1994年 | 282篇 |
1993年 | 246篇 |
1992年 | 176篇 |
1991年 | 146篇 |
1990年 | 112篇 |
1989年 | 68篇 |
1988年 | 65篇 |
1987年 | 49篇 |
1986年 | 40篇 |
1985年 | 41篇 |
1984年 | 35篇 |
1983年 | 11篇 |
1982年 | 11篇 |
1981年 | 14篇 |
1980年 | 7篇 |
1979年 | 8篇 |
1978年 | 3篇 |
1977年 | 4篇 |
1974年 | 4篇 |
1973年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 125 毫秒
71.
72.
A. Shaporenko A. Terfort M. Grunze M. Zharnikov 《Journal of Electron Spectroscopy and Related Phenomena》2006
Analysis of photoemission spectra of complex thioaromatic self-assembled monolayers (SAMs) requires the knowledge and understanding of such spectra for the basic systems. Keeping this goal in mind, synchrotron-based high-resolution X-ray photoelectron spectroscopy was used to characterize SAMs formed from the simplest thioaromatic compounds, namely thiophenol, 1,1′-biphenyl-4-thiol and 1,1′;4′,1″-terphenyl-4-thiol on evaporated Au(1 1 1) and Ag(1 1 1) substrates. The acquired S 2p and C 1s spectra were analyzed in terms of fine structure and initial and final state effects in the photoemission process. The assignment of the individual spectral features was considered in detail. Conclusions on quality and chemical and structural homogeneity of the investigated SAMs were derived. 相似文献
73.
Yi-Shiue Lin 《Applied Surface Science》2006,252(16):5892-5899
Dissociative adsorption of CCl4 on TiO2 at 35 °C has been studied by Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and electron spin resonance. CCl4 decompose to form CO, CO2, and CO3 on the surface, at such a low temperature, in which CO2 formation is not from CO oxidation on TiO2, but CO3 can be produced by CO and CO2 adsorption. The Cl generated from CCl4 decomposition is left on the surface and bonded to titanium ions. Mineralization of CCl4 on TiO2 involves the lattice oxygens. Thermodynamical driving force and possible reaction routes for CO and CO2 formation in the CCl4 decomposition on TiO2 are discussed. 相似文献
74.
Sadaharu Jo 《Applied Surface Science》2006,252(10):3514-3519
The morphologies and lattice structures of anthracene single crystals grown from the vapor phase were investigated using optical microscopy, phase contrast microscopy, atomic force microscopy (AFM), and X-ray diffraction analysis. Common morphologies with hexagonal large planes were observed irrespective of crystal size. The observation of certain surface morphologies with a phase contrast microscopy revealed that the spiral steps originated from screw dislocations present on the (0 0 1) planes. Moreover, the center and edge of the (0 0 1) planes had large curvatures, similar to hills. Resultantly, quarter-monolayer (ML) steps were observed on the large and flat planes between both hills. 相似文献
75.
研制了一台五通道ROSS-FILTER-PIN软X射线能谱仪,能谱范围为0.28—1.56keV.它由5个连续能段组成,每个能段的起止边由罗斯滤片对(ROSS-FILTERS)的L或K吸收边确定.罗斯滤片对的厚度通过优化计算得到,为了使每个通道的灵敏区外响应(即所测能段外响应)与通道总响应之比最小,在滤片对的第二滤片上镀上了一定厚度的第一滤片材料;为了缩减滤片表面积以增强低能滤片的抗冲击能力及方便滤片加工,能谱仪采用了小探测面积的PIN探测器(1mm2).借助此能谱仪,测量得到了喷气式Z箍缩(Z-pinch)等离子体辐射软X射线能谱的分布,并研究了软X射线产额随箍缩状况的变化趋势.
关键词:
Z箍缩等离子体
罗斯滤片
软X射线能谱 相似文献
76.
We report spectroscopic characterization of epitaxial YBCO thin films grown on LaAlO3 by pulsed laser deposition. Raman spectroscopy and spectroscopic ellipsometry were used for film characterization and the results were correlated with X-ray diffraction measurements. The mentioned techniques allowed us to analyze crystallographic, micro-structural, and morphological properties of YBCO thin films. We also demonstrated that relatively low resolution Raman spectroscopy and spectroscopic ellipsometry are reliable techniques for a rapid and non-destructive characterization of epitaxial YBCO thin films. 相似文献
77.
Kristin Fischer Silvio Prause Stefan Spange Frank Cichos Christian Von Borczyskowski 《Journal of Polymer Science.Polymer Physics》2003,41(11):1210-1218
Solvent‐dependent ultraviolet–visible (UV–vis) absorption and Stokes shifts including strong hydrogen‐bond‐donating (HBD) solvents such as 2,2,2‐trifluoroethanol and 1,1,1,3,3,3‐hexafluoro‐2‐propanol of two coumarine dyes (Co 151 and Co 153) were analyzed with multiple‐square analyses of linear solvation energy relationships and the Kamlet–Taft solvent parameter set to α (HBD capacity), β (hydrogen‐bond‐accepting capacity), and π* (dipolarity/polarizability). The UV–vis absorption and emission spectra of Co 151 and Co 153 were measured when adsorbed on various polysaccharides such as different cellulose batches, carboxymethylcelluloses with different degrees of substitution, and chitine. As a result of this evaluation, Co 153 is recommended as an alternative UV–vis probe for evaluating the dipolarity/polarizability of cellulose and cellulose derivates. Multiple adsorption of Co 153 on Linters cellulose took place indicating a wide‐surface polarity distribution, which makes the determination of a rigid polarity parameter questionable. Thus, fluorescence measurements of adsorbed Co 153 are suitable to detect inhomogenities on a surface but not for the determination of empirical polarity parameters. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1210–1218, 2003 相似文献
78.
Faitel'son E. A. Korkhov V. P. Aniskevich A. N. Starkova O. A. 《Mechanics of Composite Materials》2004,40(1):57-66
The results of a complex study of structural changes in a cured Norpol 440 polyester resin under the action of damp environment and mechanical loading are presented. A considerable effect of absorbed moisture on the structure and some characteristics of the material is revealed by using thermophysical methods and X-ray diffractometry. The joint effect of moisture and mechanical stress is estimated by investigating the creep in stationary and nonstationary moisture conditions. The anisotropy of the material structure formed during creep is evaluated from the results of dilatometric measurements. It is found that the degree of anisotropy of the material after creep accompanied by moisture sorption is higher than that after creep in the conditions of moisture equilibrium with atmosphere. It is established that the aftercure and relaxation of the residual creep deformation come to an end at heating to 80-85°C. At a further rise in temperature and repeated heating, changes in the material structure are not observed. 相似文献
79.
S. S. Andreev A. D. Akhsakhalyan M. A. Bibishkin N. I. Chkhalo S. V. Gaponov S. A. Gusev E. B. Kluenkov K. A. Prokhorov N. N. Salashchenko F. Schafers S. Yu. Zuev 《Central European Journal of Physics》2003,1(1):191-209
We present research investigations in the field of multilayer optics in X-ray and extreme ultra-violet ranges (XUV), aimed
at the development of optical elements for applications in experiments in physics and in scientific instrumentation. We discuss
normal incidence multilayer optics in the spectral region of “water window”, multilayer optics for collimation and focusing
of hard X-ray, multilayer dispersing elements for X-ray spectroscopy of high-temperature plasma, multilayer dispersing elements
for analysis of low Z-elements. Our research pays special attention to optimization of multilayer optics for projection EUV-lithography
(ψ-13nm) and short period multilayer optics. 相似文献
80.
Influence of annealing and chain defects on the melting behaviour of poly(vinylidene fluoride) 总被引:2,自引:0,他引:2
C. Marega 《European Polymer Journal》2003,39(8):1713-1720
The melting behaviour of poly(vinylidene fluoride) (PVDF) was investigated by differential scanning calorimetry (DSC) and small- and wide-angle X-ray scattering in order to study the influence of the chain defects content and of the temperature of annealing on the crystallization and melting behaviour.All the DSC scans show a double endotherm and the analysis of the data suggests that the low temperature endotherm is due to the melting of a population of thin lamellae, whose thickness increases during the annealing, but a high content of chain defects prevents the lamellar thickening and the main effect in this case is the crystallization of thin lamellae from a portion of polymer which did not crystallize during the quenching from the melt. Furthermore, the two melting endotherms, which are observed, can be partially ascribed to a melting-recrystallization process.Furthermore, stepwise isothermal cooling was performed in a differential scanning calorimeter followed by melting scans of fractionated PVDF samples to point out the possible presence of a series of endothermic peaks. 相似文献